How to prepare your own solutions for EC meter calibration

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On a recent post I talked about how you can prepare your own solutions for the calibration of your pH meter. However hydroponic growers not only need to calibrate their pH meters but they also need to use EC meters to control their growing environment. Today I want to talk about how you too can prepare solutions for the calibration of your EC meter so that you don’t need to depend on expensive commercially prepared solutions for EC calibration. I will also give you some important tips about how to maintain these solutions so that they last for a longer time period.

As in the case of pH meters the correct calibration of an EC meter ideally requires the use of two solutions. Most people however use only one solution or use two solutions in a rather wide range. Ideally both solutions would need to be within the range in which we would want to measure so ideally we would want to have solutions in the 0.5-3.0 ms/cm range for the calibration of an EC meter used in hydroponic. We also need to make sure we use substances that show both a linear relationship between EC and concentration and that do not affect the pH of the solution considerably as the EC can also vary significantly with the pH of a solution.

As in the case of pH meters the easiest – but definitely not most analytically correct – way to carry out this preparation is to work with a calibrated EC meter to start with. In order to do this buy a single calibration solution so that you can ensure that your EC meter is at least calibrated properly over a single point. After the EC meter is calibrated we will use it to prepare a calibration solution with a specific EC level that we can then use for calibration. Since there is nothing special about any specific EC points – not the same case as with pH electrodes where pH 7 is the electrodes isoelectric point – preparing EC calibration solutions is easier.

Start with a water source – distilled would be preferred – and add around 1g per liter of NaCl, you can use any store-bought variety to carry out this process (the small amounts of additives won’t affect this process significantly). This should give you a conductivity reading in the range that is generally used in hydroponics, depending on your tap water it should be somewhere between 1.5-2.5 mS/cm. You can also prepare another solution with 0.5g per liter of NaCl which should allow you to perform a two solution calibration. Note that the addition values do not need to be exact. If you are using tap water make sure you let it sit for around a day before using it so that any chlorine is eliminated from the water.

After preparing the solutions take note of their EC levels, these are the levels you will use for calibration. A problem with EC solutions is that they have a fundamental dependence on the concentration of ions in solution and cannot compensate for this so the EC values will vary and become unknown if you let the solutions evaporate. When storing EC solutions it is therefore important to use airtight containers and additionally put electrical tape around the cap after every use, this will make sure that the loss of ions within the bottle is minimal. After some volume of solution is used make sure you discard it and never put it back inside the same bottle.

As in the case of pH meter calibration solution preparation this is definitely not the way in which these solutions would be prepared in a lab – as you can prepare solutions with extremely accurate predicted conductivity if you have very pure salts and double distilled water – but it’s a very good way to create cheap calibration solutions that offer low enough errors to allow for their use in hydroponic culture.

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7 Comments

  • rain
    October 13, 2022 @ 11:54 am

    we took note of the EC levels of the two solution, then what?

    • admin
      October 14, 2022 @ 11:11 am

      Then use them for calibration.

      • rain
        October 14, 2022 @ 12:05 pm

        Thanks! but I meant, what do we do next? how do we calibrate? is it the same with one that uses a linear function of two concentrations where x axis is the concentration and y is the meter reading? im don’t know what its called 😂

  • Bill
    December 31, 2022 @ 7:46 pm

    Excellent post Dr. Fernandez! For those that don’t know, Dr. Fernandez also did a great YouTube video on the same subject!
    https://youtu.be/efEdmZfRRrs

    I find it interesting the formula for the Molar concentration (M/liter) of NaCl for a given EC (mS/cm) is slightly different in the graph above vs the YouTube video. I ended up using the formula in the video comments.
    The graph above – NaCl Molar concentration = (EC-0.0433)/111.41
    YouTube Video – NaCl Molar concentration = (EC-0.0126)/117
    Since the molar mass of NaCl is 58.443 g/mol, the weight (grams) of salt we need for an EC of 2.000 mS/cm in 250ml of distilled water = 58.443 x 0.250L H2O x ((2.000 – 0.0126)/117) = 0.248g

    I used canning salt (no iodine or anti-caking agents) following Dr. Fernandez instructions and found out that my inexpensive TDS meter was reading 0.3 mS/cm low and it would not let me calibrate right to 2.0 mS/cm. I think this is because the inexpensive $20 meter is designed for measuring EC at much lower salt concentrations in drinking water. On the bottom end, the meter is able to be calibrated (simple offset) at an EC of 1.0 mS/cm. I guess the moral of the story is that EC meters that let you do a 2-point or 3-point calibration are worth getting.

    I wonder if the NaCl Molar concentration vs EC is fairly linear all the way up to an EC of 12.88 mS/cm?

    Kind regards, Bill

    • Bill
      January 14, 2023 @ 7:11 pm

      To follow-up, I purchased a second EC meter (InkBird ITDS-01) to compare against my less expensive YL-TDS2-A meter. Both meters have a non-linear response to calibration solutions > 2000 µS/cm and accuracy suffers above this level. My nutrient solutions are typically 1000 to 3000 µS/cm and I decided to calibrate my meters for 2000 µS/cm. I looked at several calibration solutions that listed the concentration of salts on the label and also found the following chart in an EC probe calibration manual.

      EC @ 25°C ___ KCl ________ NaCl
      µS/cm _______ mg/L _______ mg/L
      23 __________ 11.6 _______ 10.7
      84 __________ 40.38 ______ 38.04
      447 _________ 226 ________ 215
      1413 ________ 746 ________ 702 (Note, KCl was reduced to 716 mg/L to remain linear)
      1500 ________ 757 ________ 737
      2070 ________ 1045 _______ 1041
      2764 ________ 1382 _______ 1414
      8974 ________ 5101 _______ 4487 (Note, NaCl was increased to 4915 mg/L to remain linear)
      12880 _______ 7447 _______ 7230
      15000 _______ 8759 _______ 8532
      80000 _______ 52168 ______ 48384

      Plotting the values between 23 and 2764 µS/cm, gave a linear trend that I used to make up my calibration solutions. For KCl, I used 4020 mg/L for a target of 8003 µS/cm @ 25°C. I took measurements then poured out 1/2 of the solution and replenished the full volume with distilled water. The new solution was stirred and heated back to 25°C the EC now should be 4000 µS/cm for the next measurement. Cutting the volume in half again and replacing with more distilled water brings the EC to 2000 µS/cm @ 25°C. This is where I calibrated the meters. The YL-TDS2-A does not have enough adjustment range to calibrate to 2000 µS/cm but the InkBird does. I repeated this process using NaCl starting with 4033 mg/L for a target of 7940 µS/cm @ 25°C. Cutting this solution concentration in half gives 3980 µS/cm and then half again gives 2000 µS/cm for a calibration point.

      The calibration solution formulas I used are the following.
      Where:
      EC is expressed in µS/cm
      KCl mg/L = ((EC +2.6)/148479)* 74.5513 * 1000mL
      NaCl mg/L = ((EC -20)/114769)* 58.4428 * 1000mL

      Regards, Bill

    • Bill
      April 5, 2023 @ 8:20 am

      I have made EC calibration solution a few times now and have better luck weighing everything since I do not own a volumetric flask. I formulate a stock salt solution with a calculated molar concentration about 2X greater than I need. Since NaCl displaces water, I subtract 0.87mL per gram of salt from the final volume and calculate the required water weight using 0.997g / ml H2O. I then use the dilution equation to make the desired calibration solution from the stock solution. The average I have done so far with this method has been within ~ 2% desired EC as compared with a NIST traceable calibration solution which is close enough for my needs. Using the same scale for the whole process really helps keep the salt to water ratio where you want it.

    • Bill
      April 5, 2023 @ 8:40 am

      Correction, I shoot for a stock solution molar concentration about 5 X greater than I need for the calibration solution. I found that 0.1 moles / Liter NaCl (EC 11,497 uS/cm) works well. For a 200mL stock solution I used 1.17g NaCl plus 199.56g H2O. To create 200mL of 1413 uS/cm cal solution, I used 24.22g of stock solution plus 175.2g of H2O.

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